Browsing by Author "Noubactep, Chicgoua"

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Application of the Kilimanjaro Concept in Reversing Seawater Intrusion and Securing Water Supply in Zanzibar, Tanzania
(MDPI, 2021-07-30) Pembe-Ali, Zuleikha; Mwamila, Tulinave; Lufingo, Mesia; Gwenzi, Willis; Marwa, Janeth; Rwiza, Mwemezi; Lugodisha, Innocent; Qi, Qinwen; Noubactep, Chicgoua
There is escalating salinity levels on small islands due to uncontrolled groundwater extraction. Conventionally, this challenge is addressed by adopting optimal groundwater pumping strategies. Currently, on Unguja Island (Zanzibar), urban freshwater is supplied by desalination, which is expensive and energy-intensive. Hence, desalinization cannot be afforded by rural communities. This study demonstrates that the innovative Kilimanjaro Concept (KC), based on rainwater harvesting (RWH) can remediate seawater intrusion in Unguja, while enabling a universal safe drinking water supply. The reasoning is rooted in the water balance of the whole island. It is shown that if rainwater is systematically harvested, quantitatively stored, and partly infiltrated, seawater intrusion will be reversed, and a universal safe drinking water supply will be secured. Water treatment with affordable technologies (e.g., filtration and adsorption) is suggested. The universality of KC and its suitability for small islands is demonstrated. Future research should focus on pilot testing of this concept on Unguja Island and other island nations.
Avoiding the Use of Exhausted DrinkingWater Filters: A Filter-Clock Based on Rusting Iron
(MDPI, 2018-05-02) Ndé-Tchoupé, Arnaud Igor; Lufingo, Mesia; Hu, Rui; Gwenzi, Willis; Ntwampe, Seteno Karabo Obed; Noubactep, Chicgoua; Njau, Karoli
Efficient but affordable water treatment technologies are currently sought to solve the prevalent shortage of safe drinking water. Adsorption-based technologies are in the front-line of these efforts. Upon proper design, universally applied materials (e.g., activated carbons, bone chars, metal oxides) are able to quantitatively remove inorganic and organic pollutants as well as pathogens from water. Each water filter has a defined removal capacity and must be replaced when this capacity is exhausted. Operational experience has shown that it may be difficult to convince some low-skilled users to buy new filters after a predicted service life. This communication describes the quest to develop a filter-clock to encourage all users to change their filters after the designed service life. A brief discussion on such a filter-clock based on rusting of metallic iron (Fe0) is presented. Integrating such filter-clocks in the design of water filters is regarded as essential for safeguarding public health.
Conceptualizing the Fe0/H2O System: A Call for Collaboration to Mark the 30th Anniversary of the Fe0-Based Permeable Reactive Barrier Technology
(MDPI, 2022-10-03) Cao, Viet; Bakari, Omari; Tchidjo, Joseline; Bandjun, Nadège; Tchoupé, Arnaud; Gwenzi, Willis; Njau, Karoli; Noubactep, Chicgoua
Science denial relates to rejecting well-established views that are no longer questioned by scientists within a given community. This expression is frequently connected with climate change and evolution. In such cases, prevailing views are built on historical facts and consensus. For water remediation using metallic iron (Fe0), also known as the remediation Fe0/H2O system, a consensus on electro-chemical contaminant reduction was established during the 1990s and still prevails. Arguments against the reductive transformation concept have been regarded for more than a decade as ‘science denial’. However, is it the prevailing concept that denies the science of aqueous iron corrosion? This article retraces the path taken by our research group to question the reductive transformation concept. It is shown that the validity of the following has been questioned: (i) analytical applications of the arsenazo III method for the determination of uranium, (ii) molecular diffusion as sole relevant mass-transport process in the vicinity of the Fe0 surface in filtration systems, and (iii) the volumetric expansive nature of iron corrosion at pH > 4.5. Item (i) questions the capability of Fe0 to serve as an electron donor for UVI reduction under environmental conditions. Items (ii) and (iii) are inter-related, as the Fe0 surface is permanently shielded by a non-conductive oxide scale acting as a diffusion barrier to dissolved species and a barrier to electrons from Fe0. The net result is that no electron transfer from Fe0 to contaminants is possible under environmental conditions. This conclusion refutes the validity of the reductive transformation concept and calls for alternative theories.
Defeating Fluorosis in the East African Rift Valley: Transforming the Kilimanjaro into a Rainwater Harvesting Park
(MDPI, 2018-11-14) Marwa, Janeth; Lufingo, Mesia; Noubactep, Chicgoua; Machunda, Revocatus
The high availability of fluoride in surface and groundwater in the East African Rift Valley was documented during the colonial period. Since the early 1960s, many studies have been conducted to solve the fluorosis crisis in this region. At present, no cost-effective solution to mitigate fluoride contamination is available for the large majority of the population. This situation prompted a process analysis of commonly used technologies. Results revealed that the geochemistry of fluoride is the main problem. Fluoride is very difficult to remove from the aqueous phase. Thus, eliminating the need for technical water defluoridation is an excellent way out of the fluorosis crisis. This goal can be achieved by harvesting fluoride-free rainwater. Harvested rainwater can be mixed with naturally polluted waters in calculated proportions to obtain safe drinking water (blending). This paper presents a concept to transform the Kilimanjaro Mountains into a huge rainwater harvesting park for drinking water supply for the whole East African Rift Valley. However, blended water may contain other pollutants including pathogens that are easy to treat using low-cost methods such as metallic iron based-filters (Fe0 filters). The proposed concept is transferable to other parts of the world still enduring fluoride pollution.
Effects of zero-valent iron on sludge and methane production in anaerobic digestion of domestic wastewater
(Elsevier, 2023-12-08) Bakari, Omari; Njau, Karoli; Noubactep, Chicgoua
Iron metal (Fe0) materials enhance the performance of anaerobic digestion (AD) reactors to remove pollutants. Most research focused on the materials' mechanisms and effectiveness in enhancing AD. However, there is scant information on the biogas and sludge quality and quantity and the kinetics of generated methane (CH4) of biogas from the Fe0-aided AD of domestic wastewater (DW). The information is essential for AD reactors' management. This study characterizes the sludge and biogas from Fe0-aided AD of DW and predicts the CH4 yield using the Gompertz, Logistic, and Richard models to study the impact of Fe0 materials on the composition and generation of sludge and biogas. Bench-scale reactors containing DW were fed with Fe0 and operated for 53 days in a quiescent condition, at 24 ± 3 OC room temperature, at 7.3 initial pH value. Steel wool and iron scrap were used as Fe0 sources. A parallel experiment without Fe0 was performed as an operational reference. Results indicate that Fe0 significantly enriched most of the nutrients in sludges, produced well-settling sludge (sludge volume index ≤30), and enriched the CH4 of biogas by more than 12%. Furthermore, all the tested models exhibited good fitting (error <10%) in predicting CH4 production. Fe0-aided AD produced a sludge with the potential for application in agricultural land and increased the heating value of the biogas by enriching the CH4. More than 80% of particles generated from Fe0-aided AD of DW can be settled in sedimentation tanks designed at an overflow rate ≤40 m/d. Richard was the best model for predicting methane yield from Fe0-aided AD of DW (error <1.6%).
Fe0-Supported Anaerobic Digestion for Organics and Nutrients Removal from Domestic Sewage
(MDPI, 2022-08-15) Bakari, Omari; Njau, Karoli; Noubactep, Chicgoua
results from different research suggest that metallic iron (Fe0) materials enhance anaerobic digestion (AD) systems to remove organics (chemical oxygen demand (COD)), phosphorus and nitrogen from polluted water. However, the available results are difficult to compare because they are derived from different experimental conditions. This research characterises the effects of Fe0 type and dosage in AD systems to simultaneously remove COD and nutrients (orthophosphate (PO43−), ammonium (NH4+), and nitrate (NO3−)). Lab-scale reactors containing domestic sewage (DS) were fed with various Fe0 dosages (0 to 30 g/L). Batch AD experiments were operated at 37 ± 0.5 °C for 76 days; the initial pH value was 7.5. Scrap iron (SI) and steel wool (SW) were used as Fe0 sources. Results show that: (i) SW performed better than SI on COD and PO43− removal (ii) optimum dosage for the organics and nutrients removal was 10 g/L SI (iii) (NO3− + NH4+) was the least removed pollutant (iv) maximum observed COD, PO43− and NO3− + NH4+ removal efficiencies were 88.0%, 98.0% and 40.0% for 10 g/L SI, 88.2%, 99.9%, 25.1% for 10 g/L SW, and 68.9%, 7.3% and 0.7% for the reference system. Fe0-supported AD significantly removed the organics and nutrients from DS
Making Rainwater Harvesting a Key Solution for Water Management: The Universality of the Kilimanjaro Concept
(MDPI, 2019-10-11) Qi, Qinwen; Marwa, Janeth; Mwamila, Tulinave Burton; Gwenzi, Willis; Noubactep, Chicgoua
Rainwater is conventionally perceived as an alternative drinking water source, mostly needed to meet water demand under particular circumstances, including under semi-arid conditions and on small islands. More recently, rainwater has been identified as a potential source of clean drinking water in cases where groundwater sources contain high concentrations of toxic geogenic contaminants. Specifically, this approach motivated the introduction of the Kilimanjaro Concept (KC) to supply fluoride-free water to the population of the East African Rift Valley (EARV). Clean harvested rainwater can either be used directly as a source of drinking water or blended with polluted natural water to meet drinking water guidelines. Current e orts towards the implementation of the KC in the EARV are demonstrating that harvesting rainwater is a potential universal solution to cover ever-increasing water demands while limiting adverse environmental impacts such as groundwater depletion and flooding. Indeed, all surface and subsurface water resources are replenished by precipitation (dew, hail, rain, and snow), with rainfall being the main source and major component of the hydrological cycle. Thus, rainwater harvesting systems entailing carefully harvesting, storing, and transporting rainwater are suitable solutions for water supply as long as rain falls on earth. Besides its direct use, rainwater can be infiltrating into the subsurface when and where it falls, thereby increasing aquifer recharge while minimizing soil erosion and limiting floods. The present paper presents an extension of the original KC by incorporating Chinese experience to demonstrate the universal applicability of the KC for water management, including the provision of clean water for decentralized communities.
Metallic iron for safe drinking water provision: Considering a lost knowledge
(Pergamon, 2017-06-15) Mwakabona, Hezron; Ndé-Tchoupé, Arnaud; Njau, Karoli; Noubactep, Chicgoua; Wydra, Kerstin
Around year 1890, the technology of using metallic iron (Fe0) for safe drinking water provision was already established in Europe. The science and technology to manufacture suitable Fe0 materials were known and further developed in this period. Scientists had then developed skills to (i) explore the suitability of individual Fe0 materials (e.g. iron filling, sponge iron) for selected applications, and (ii) establish treatment processes for households and water treatment plants. The recent (1990) discovery of Fe0 as reactive agent for environmental remediation and water treatment has not yet considered this ancient knowledge. In the present work, some key aspects of the ancient knowledge are presented together with some contemporised interpretations, in an attempt to demonstrate the scientific truth contained therein. It appears that the ancient knowledge is an independent validation of the scientific concept that in water treatment (Fe0/H2O system) Fe0 materials are generators of contaminant collectors.
Metallic iron for water treatment: leaving the valley of confusion
(Springer, 2017-07-31) Makota, Susanne; Nde-Tchoupe, Arnaud; Mwakabona, Hezron; Noubactep, Chicgoua; Nassi, Achille; Njau, Karoli; Mwakabona, Hezron
Researchers on metallic iron (Fe0) for environmental remediation and water treatment are walking in a valley of confusion for 25 years. This valley is characterized by the propagation of different beliefs that have resulted from a partial analysis of the Fe0/H2O system as (1) a reductive chemical reaction was considered an electrochemical one and (2) the mass balance of iron has not been really addressed. The partial analysis in turn has been undermining the scientific method while discouraging any real critical argumentation. This communication re-establishes the complex nature of the Fe0/H2O system while recalling that, finally, proper system analysis and chemical thermodynamics are the most confident ways to solve any conflicting situation in Fe0 environmental remediation.
A Novel and Facile Method to Characterize the Suitability of Metallic Iron for Water Treatment
(MDPI, 2019-11-23) Lufingo, Mesia; Ndé-Tchoupé, Arnaud Igor; Hu, Rui; Njau, Karoli; Noubactep, Chicgoua
Metallic iron (Fe0) materials have been industrially used for water treatment since the 1850s. There are still many fundamental challenges in affordably and reliably characterizing the Fe0 intrinsic reactivity. From the available methods, the one using Fe0 dissolution in ethylenediaminetetraacetic acid (EDTA—2 mM) was demonstrated the most applicable as it uses only four affordable chemicals: Ascorbic acid, an ascorbate salt, EDTA and 1,10-Phenanthroline (Phen). A careful look at these chemicals reveals that EDTA and Phen are complexing agents for dissolved iron species. Fe3-EDTA is very stable and difficult to destabilize; ascorbic acid is one of the few appropriate reducing agents, therefore. On the other hand, the Fe2-Phen complex is so stable that oxidation by dissolved O2 is not possible. This article positively tests Fe0 (0.1 g) dissolution in 2 mM Phen (50 mL) as a characterization tool for the intrinsic reactivity, using 9 commercial steel wool (Fe0 SW) specimens as probe materials. The results are compared with those obtained by the EDTA method. The apparent iron dissolution rate in EDTA (kEDTA) and in Phen (kPhen) were such that 0.53 ≤ kEDTA (μg h−1) ≤ 4.81 and 0.07 ≤ kPhen (μg h−1) ≤ 1.30. Higher kEDTA values, relative to kPhen, are a reflection of disturbing Fe3 species originating from Fe2 oxidation by dissolved O2 and dissolution of iron corrosion products. It appears that the Phen method considers only the forward dissolution of Fe0. The Phen method is reliable and represents the most affordable approach for characterizing the suitability of Fe0 for water treatment.
White Teeth and Healthy Skeletons for All: The Path to Universal Fluoride-Free DrinkingWater in Tanzania
(MDPI, 2019-01-12) Ndé-Tchoupé, Arnaud Igor; Tepong-Tsindé, Raoul; Lufingo, Mesia; Pembe-Ali, Zuleikha; Lugodisha, Innocent; Mureth, Risala Iddi; Nkinda, Mihayo; Marwa, Janeth; Gwenzi, Willis; Mwamila, Tulinave Burton; Rahman, Mohammad Azizur; Noubactep, Chicgoua; Njau, Karoli
Fluorosis has been prevalent in the great East African Rift Valley (EARV) since before this region was given a name. In the Tanganyika days, Germans reported elevated fluoride concentrations in natural waters. In the 1930s, the clear relationship between high fluoride level and mottling of teeth was established. Since then, the global research community has engaged in the battle to provide fluoride-free drinking water, and the battle is not yet won for low-income communities. An applicable concept for fluoride-free drinking water in the EARV was recently presented, using the Kilimanjaro as a rainwater harvesting park. The Kilimanjaro concept implies that rainwater is harvested, stored on the Kilimanjaro mountains, gravity-transported to the point of use, eventually blended with natural water and treated for distribution. This article provides a roadmap for the implementation of the Kilimanjaro concept in Tanzania. Specifically, the current paper addresses the following: (i) presents updated nationwide information on fluoride contaminated areas, (ii) discusses the quality and quantity of rainwater, and current rainwater harvesting practices in Tanzania, (iii) highlights how low-cost water filters based on Fe0/biochar can be integrating into rainwater harvesting (RWH) systems to provide clean drinking water, and (iv) discusses the need for strict regulation of RWH practices to optimize water collection and storage, while simplifying the water treatment chain, and recommends strict analytical monitoring of water quality and public education to sustain public health in the EARV. In summary, it is demonstrated that, by combining rainwater harvesting and low-cots water treatment methods, the Kilimanjaro concept has the potential to provide clean drinking water, and overcome fluorosis on a long-term basis. However, a detailed design process is required to determine: (i) institutional roles, and community contributions and participation, (ii) optimal location and sizing of conveyance and storage facilities to avoid excessive pumping costs, and (iii) project funding mechanisms, including prospects for government subsidy. By drawing attention to the Kilimanjaro concept, the article calls for African engineers and scientists to take the lead in translating this concept into reality for the benefit of public health, while simultaneously increasing their self-confidence to address other developmental challenges pervasive in Africa.