Research Articles [MEWES]
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Item Accounting for Seasonal Land Use Dynamics to Improve Estimation of Agricultural Irrigation Water Withdrawals(MDPI, 2019-11-24) Msigwa, Anna; Komakech, Hans; Verbeiren, Boud; Salvadore, Elga; Hessels, Tim; Weerasinghe, Imeshi; van Griensven, AnnThe assessment of water withdrawals for irrigation is essential for managing water resources in cultivated tropical catchments. These water withdrawals vary seasonally, driven by wet and dry seasons. A land use map is one of the required inputs of hydrological models used to estimate water withdrawals in a catchment. However, land use maps provide typically static information and do not represent the hydrological seasons and related cropping seasons and practices throughout the year. Therefore, this study assesses the value of seasonal land use maps in the quantification of water withdrawals for a tropical cultivated catchment. We developed land use maps for the main seasons (long rains, dry, and short rains) for the semi-arid Kikuletwa catchment, Tanzania. Three Landsat 8 images from 2016 were used to develop seasonal land use land cover (LULC) maps: March (long rains), August (dry season), and October (short rains). Quantitative and qualitative observation data on cropping systems (reference points and questionnaires/surveys) were collected and used for the supervised classification algorithm. Land use classifications were done using 20 land use and land cover classes for the wet season image and 19 classes for the dry and short rain season images. Water withdrawals for irrigated agriculture were calculated using (1) the static land use map or (2) the three seasonal land use maps. Clear differences in land use can be seen between the dry and the other seasons and between rain-fed and irrigated areas. A difference in water withdrawals was observed when seasonal and static land use maps were used. The highest differences were obtained for irrigated mixed crops, with an estimation of 572 million m3/year when seasonal dynamic maps were used and only 90 million m3/year when a static map was used. This study concludes that detailed seasonal land use maps are essential for quantifying annual irrigation water use of catchment areas with distinct dry and wet seasonal dynamics.Item Activated Bentonite for Physical, Mechanical, and Durability Properties of Concrete—A Review(Wiley, 2024-12) Fode, Tsion; Jande, Yusufu; Kivevele, ThomasBentonite mostly exists in many counties and studies reported employment of activated bentonite in the concrete improves concrete performance more than using raw bentonite. However, it is not well-known which range of bentonite activation temperature and employment dose gives the best concrete performance for the sustainability of activated bentonite in construction materials. Therefore, the present study detail reviewed the effect of activated bentonite at different heating temperatures and replacement doses of bentonite on the durability, physical, mechanical, and microstructural properties of concrete. Also, environmental and economic beneficiary of employing activated bentonite in concrete is evaluated. As the review of various studies reveals, activation of bentonite between 201 and 800°C increases the pozzolanic reactivity of bentonite. Hence, the activated pozzolana can easily consume free calcium hydroxide to form a secondary C–S–H gel that can improve the mechanical, microstructural, and durability properties of activated bentonite blended concrete in addition to lessening energy consumption compared to conventional concrete. Besides these, adding 15%–20% of activated bentonite in concrete significantly improves the mechanical properties; specifically, most studies found the optimum activated bentonite dose is 15% by weight of cement in concrete. This replacement indicates lessened energy consumption by around 45% compared to the total employment of ordinary Portland cement in concrete production.Item Adsorption and desorption ability of divalent mercury from an interactive bicomponent sorption system using hybrid granular activated carbon(Springer International Publishing, 2023-09) Jonas, Bayuo; Rwiza, Mwemezi; Mtei, KelvinThe sequestration of heavy metals from multicomponent sorption media has become critical due to the noxious effects of heavy metals on the natural environment and subsequently on human health as well as all life forms. The abatement of heavy metals using bio-adsorbents is one of the efficient and affordable approaches for treating water and wastewater. Therefore, the interactive effect of arsenic [As(III)] ions on the sorption and desorption ability of mercury [Hg(II)] from a binary sorption system was conducted. More so, the impact of reaction time, solution pH, bio-adsorbent particle size, bio-adsorbent dose, initial mono-metal, and binary-metal concentration as well as reaction temperature on the individual and competitive sorption of Hg(II) was explored. The study showed that Hg(II) could be removed effectively from the single-component system and competitively from the aqueous phases by the bio-adsorbent in the coexistence of As(III) species in the bicomponent medium. The adsorptive detoxification of Hg(II) from the monocomponent and bicomponent sorption media showed dependence on all the studied adsorption parameters. The occurrence of As(III) species in the bicomponent sorption medium affected the decontamination of Hg(II) by the bio-adsorbent and the major interactive mechanism was found to be antagonism. The spent bio-adsorbent was effectively recycled using 0.10 M nitric (HNO3) and hydrochloric (HCl) acids solutions and the multi-regeneration cycles showed a high removal efficiency in each cycle. The first regeneration cycle was found to have the highest Hg(II) ions removal efficiencies of 92.31 and 86.88% for the monocomponent and bicomponent systems, respectively. Thus, the bio-adsorbent was found to be mechanically stable and reusable up to the 6.00 regeneration cycle. Therefore, this study concludes that the bio-adsorbent not only has a higher adsorption capacity but also a good recycling performance pointing to good industrial applications and economic prospects.Item Adsorption and desorption processes of toxic heavy metals, regeneration and reusability of spent adsorbents: Economic and environmental sustainability approach(Elsevier, 2024-05-19) Bayuo, Jonas; Rwiza, Mwemezi; Choi, Joon; Mtei, Kelvin; Hosseini-Bandegharaei, Ahmad; Sillanpää, MikaA growing number of variables, including rising population, water scarcity, growth in the economy, and the existence of harmful heavy metals in the water supply, are contributing to the increased demand for wastewater treatment on a global scale. One of the innovative water treatment technologies is the adsorptive removal of heavy metals through the application of natural and engineered adsorbents. However, adsorption currently has setbacks that prevent its wider application for heavy metals sequestration from aquatic environments using various adsorbents, including difficulty in selecting suitable desorption eluent to recover adsorbed heavy metals and regeneration techniques to recycle the spent adsorbents for further use and safe disposal. Therefore, the recovery of adsorbed heavy metal ions and the ability to reuse the spent adsorbents is one of the economic and environmental sustainability approaches. This study presents a state-of-the-art critical review of different desorption agents that could be used to retrieve heavy metals and regenerate the spent adsorbents for further adsorption-desorption processes. Additionally, an attempt was made to discuss and summarize some of the independent factors influencing heavy metals desorption, recovery, and adsorbent regeneration. Furthermore, isotherm and kinetic modeling have been summarized to provide insights into the adsorption-desorption mechanisms of heavy metals. Finally, the review provided future perspectives to provide room for researchers and industry players who are interested in heavy metals desorption, recovery, and spent adsorbents recycling to reduce the high cost of adsorbents reproduction, minimize secondary waste generation, and thereby provide substantial economic and environmental benefits.Item Adsorption of phenol and methylene blue contaminants onto high-performance catalytic activated carbon from biomass residues(Cellpress, 2025-01-15) Bih, Numfor; Rwiza, Mwemezi; Ripanda, Asha; Mahamat, Assia; Machunda, Revocatus; Choi, JoonOrganic contaminants from wastewater toxicity to the environment has increased during the last few decades and, therefore, there is an urgent need to decontaminate wastewater prior to disposal. This study aimed to create a high surface area catalytic activated carbon (AC) under same carbonization conditions for phenol and methylene blue (organic wastewater) decontamination. Moringa oleifera husk (MH), sesame husk (SH), and baobab husk (BH) were used to prepare activated carbon for the removal of methylene blue (MB) and phenol (Ph). After characterization of the adsorbent, the BET surface areas of the M. oleifera husk activated carbon (MHC), sesame husk activated carbon (SHC), and baobab husk activated carbon (BHC) were 1902.30 m2/g, 1115.90 m2/g, and 1412.40 m2/g, respectively. Mono-adsorption and binary-adsorption systems were studied for Ph and MB adsorption. Furthermore, the effect of initial organic waste concentration, contact time, pH, temperature and AC dosage, on adsorption capacity were studied. The mono adsorption system isotherms and kinetics studies used to analyze Phenol and MB adsorption best fitted Langmuir and pseudo-second-order models. The Freundlich isotherm and pseudo-second-order model best fitted the experimental data for the binary-adsorption system. The high maximum adsorption capacities of organic waste for the single and binary systems were 352.25–855.96 mg/g and 348.90–456.39 mg/g, respectively. The results showed that the high surface activated carbon produced had the potential to adsorb high concentrations of MB and Phenol contaminants.Item Adsorption-capacitive deionization hybrid system with activated carbon of modified potential of zero charge(Elsevier, 2023-02-15) Sufiani, Omari; Elisadiki, Joyce; Tanaka, Hideki; Teshima, Katsuya; Sahini, Mtabazi; Machunda, Revocatus; Jande, YusufuIn this study water solutions are desalinated with carbon electrodes of modified surface charges. The idea is to endow the electrodes with the ability to physically adsorb salt ions without applying potential so as to save energy. The modification enhanced to decrease the energy consumption of a newly invented adsorption-CDI hybrid system by 19%, since modified activated carbon cell consumed 0.620 (relative error 3.00%) kWh/m3 compared to pristine activated carbon cell which consumed 0.746 (relative error 1.20%) kWh/m3. Further analysis revealed high adsorption capacity of the modified activated carbon electrode cell which exhibited 9.0 (relative error 2.22%) compared to activated carbon cell with 5.3 (relative error 5.66%) mg g−1. These results show the potential of surface modification in adding value to low cost activated carbons for application in CDI.Item Adsorptive Removal of Heavy Metals from Wastewater Using Low-Cost Adsorbents Derived from Agro-based Materials.(Springer Nature, 2024-03-29) Bayuo, Jonas; Rwiza, Mwemezi; Mtei, KelvinRecently, anthropogenic activities have evolved into sources of pollution, particularly when it comes to the discharge of harmful heavy metals into the natural environment. As a result, the concentration of diverse heavy metal ions in surface and ground waters significantly increases, compromising aquatic life. Given that toxic heavy metals have undesirable consequences on the health of all living things, their presence in the aquatic environment is a major worry. However, the drawbacks of conventional wastewater treatment technologies, such as their high consumption of energy, production of hazardous secondary sludge, and high operating costs, made them uneconomical and non-sustainable for developing nations. This book chapter presents and discusses the most recent developments and advances in the adsorptive removal of various heavy metals from aquatic systems through the application of low-cost adsorbents derived from agricultural waste materials. The influence of independent adsorption parameters as well as the mechanism of heavy metals removal from aqueous media have been explained using adsorption isotherm and kinetic models. This book chapter has demonstrated that the adsorptive removal of heavy metals using low-cost adsorbents derived from agricultural waste materials has several advantages. Almost all the studies on the adsorptive decontamination of various heavy metals from aqueous solutions revealed that adsorbents synthesized from agro-based materials are promising, eco-friendly, and cost-effective. However, several gaps exist, which need to be addressed to increase the application of the adsorption technology in treating industrial wastewater at a large scale. Hence, at the end of this book chapter, some future perspectives providing knowledge gaps that require consideration and further research have been enumerated.Item Advances in metal–organic frameworks as adsorbents, photocatalysts and membranes: a new frontier in water purification(Springer Nature Link, 2024-08-06) Kiteto, Moses; Vidija, Beryl; Mecha, Cleophas; Mrosso, Register; Chollom, MarthaWater is an essential and irreplaceable necessity for life on earth, sustaining ecosystems, nourishing agriculture and vital for human survival. However, increasing population and industrialization has exacerbated water scarcity and pollution. The Sustainable Development Goal 6 focuses on clean water and sanitation for all; thus, water purification and conservation are key priorities globally. Rampant pollution of water sources by emerging bio-recalcitrant contaminants, often deviant of conventional treatment methods, necessitates new approaches to water treatment. In this regard, metal organic frameworks (MOFs) are gaining prominence and offer solutions in versatile applications due to their unique structural characteristics and tunable properties. This review provides a comprehensive analysis of MOFs, covering their diverse structures, types, synthesis methods and characterization techniques. We explore the application of MOFs in water purification, as adsorbents, photocatalysts, and in membrane separation. The mechanism of operation of MOFs in each application is critically evaluated. The effect of the water treatment methods on energy consumption has also been investigated. We propose that for MOFs application in water treatment to be competitive and sustainable, there is need to address key issues such as synthesis of highly selective MOFs, recovery and reuse, scalability (pilot and industrial scale), and integration with existing water treatment technologies to create synergy. We provide future perspectives on these aspects. ·Item African farmer-led irrigation development: re-framing agricultural policy and investment?(Taylor & Francis online, 2016-11-09) Woodhouse, Philip; Veldwisch, Gert Jan; Brockington, Dan; Komakech, Hans; Manjichi, AngelaThe past decade has witnessed an intensifying focus on the development of irrigation in sub-Saharan Africa. It follows a 20-year hiatus in the wake of disappointing irrigation performance during the 1970s and 1980s. Persistent low productivity in African agriculture and vulnerability of African food supplies to increasing instability in international commodity markets are driving pan-African agricultural investment initiatives, such as the Comprehensive Africa Agricultural Development Programme (CAADP), that identify as a priority the improvement in reliability of water control for agriculture. The paper argues that, for such initiatives to be effective, there needs to be a re-appraisal of current dynamics of irrigation development in sub-Saharan Africa, particularly with respect to the role of small-scale producers’ initiatives in expanding irrigation. The paper reviews the principal forms such initiatives take and argues that official narratives and statistics on African irrigation often underestimate the extent of such activities. The paper identifies five key characteristics which, it argues, contradict widely held assumptions that inform irrigation policy in Africa. The paper concludes by offering a definition of ‘farmer-led irrigation’ that embraces a range of interaction between producers and commercial, government and non-government agencies, and identifies priority areas for research on the growth potential and impact of such interactions and strategies for their future development.Item Agro-Waste-Derived Hybrid Biochar Exhibits High-Efficiency Removal of Endocrine-Disrupting Compounds(Springer International Publishing, 2025-04-11) Kasambala, Hildegard; Rwiza, Mwemezi; Mpumi, Nelson; Mwema, Mwema; Njau, KaroliPoor waste management of the products and products used in water sources becomes a problem for living organisms’ health. Using biosorbent from agro-waste materials becomes the solution for waste management and wastewater treatment. This study investigated the removal of progesterone from aqueous solutions using a biochar adsorbent derived from mixed banana and mango peels. The biosorbent shows high progesterone removal of 97.8 ± 0.02% at 700℃ preparation temperature at an optimal biosorbent concentration of 0.50 g and pH of 8. Kinetic studies showed that the adsorption followed a pseudo-second-order model. Isotherm analysis revealed that the adsorption data best fitted the Freundlich model (R2 = 0.96), with a maximum adsorption capacity (qmax) of 307 mg g−1, indicating multilayer adsorption with a heterogeneous surface. The Brunauer–Emmett–Teller (BET) surface area was 652 m2g−1 with abundant functional groups verified by Fourier Transform Infrared Spectroscopy (FTIR). The Scanning Electron Microscopy image (SEM) indicated that the biochar is porous, contributing to its effectiveness as an adsorbent. Thermodynamics results indicate that the spontaneous nature of adsorption reveals the process. The findings proved the potential of using agricultural mixed waste-derived biochar containing various chemical and physical characteristics as an effective and sustainable adsorbent to remove endocrine disruptors. This technique addresses environmental concerns about water hormone pollution and promotes sustainable waste management practices, but the gradual decrease in adsorption efficiency highlights the importance of optimizing the biochar's chemical composition and structural reliability to maximize its performance.Item Agrochemicals use in horticulture industry in Tanzania and their potential impact to water resources(International Journal of Biological and Chemical Sciences, 2014-04) Lema, Emmy; Machunda, Revocatus; Njau, KaroliThe objective of this review was to analyze the existing information on the use of agrochemicals (Fertilizers and Pesticides) in the Tanzanian horticulture industry especially the Northern regions and their potential to impacting water resources. Agrochemicals play an important role in horticulture, and have been widely used in Tanzania for crop protection and increasing productivity. Apart from these benefits, agrochemicals have the potential to impair the quality of water resources for different end uses. Majority of communities in Tanzania depend on surface water from rivers and lakes for potable uses such as washing, drinking and domestic animals also drink from these sources. Reports from studies done in Northern Tanzania have indicated the presence of significant levels of pesticides, phosphates and nitrates in surface and groundwater. It is apparent that most of the horticultural farms in Northern Tanzania are located on gently sloping land adjacent to water bodies. Thus discharges of wastewaters from horticulture farms may affect the quality of water resources through run-off and groundwater through infiltration if proper management of the agrochemicals is not well adhered to. The agrochemicals that have been widely used and identified as potential environmental pollutants from their use as horticultural chemicals are reviewed. The potentially adverse impacts of these agrochemicals to water resources are discussed. The review concludes with a discussion of the directions for further investigation.Item Alternative tanning technologies and their suitability in curbing environmental pollution from the leather industry: A comprehensive review.(Elsevier Ltd., 2020-04-18) China, Cecilia; Maguta, Mihayo; Nyandoro, Stephen; Hilonga, Askwar; Kanth, Swarna; Njau, KaroliChrome tanning remains the most favourite technology in the leather industry worldwide due to its ability to produce leather with attributes desirable for high-quality leather such as excellent hydrothermal stability, better dyeing characteristics and softness. Nevertheless, the technology has been censured globally for its severe environmental detriments and adverse effects on human health and other organisms. Developing alternative eco-friendly tanning technologies capable of producing leather of high quality has remained a challenging scientific inquiry. This review article provides an assessment of various eco-friendly tanning attempts geared towards improving or replacing the chrome technology without compromising the quality of the produced leather. The reviewed publications have ascertained that, these attempts have been centred on recycling of spent liquors; chromium exhaustion enhancement and total replacement of chromium salts. The research gaps and levels of key environmental pollutants from the reviewed technologies are presented, and the qualities of the leather produced from these technologies are highlighted. Of all the examined alternative technologies, total replacement of chromium salts sounds ideal to elude adverse effects associated with chrome tanning. Combination tanning, which implies blending two tanning agents that individually cannot impart desired properties to the leather, is anticipated to be an alternative technology to chrome tanning. Apart from being an eco-friendly technology, combination tanning produces leather with similar features to those produced by chrome tanning. In this regard, blending vegetable tannins with aluminium sulphate provides a promising chrome-free tanning technology. However, further studies to optimize combination tanning technologies to suit industrial applications are highly recommended.Item Anaerobic digestion of banana winery effluent for biogas production(International Journal of Environmental Protection and Policy, 2014-09-30) Bakili, Sophia; Gessesse, Amare; Mtei, Kelvin; Njau, Karolihe efficiency of banana winery effluent (BWE) in biogas production through improving fermentation process was investigated in this study. The study was conducted in a batch system under mesophilic temperature of 35oC achieved by using controlled thermostat waterbath. Two sets of experiments (labeled as experiment 1 and experiment 2) with five reactors each, were performed in the laboratory. For experiment 1, reactor A was treated as a control with no addition of urea while 1g,2g,3g and 4g of urea were added in reactors B,C,D and E respectively. For experiment 2, different amount of sucrose, that is 0.18g, 0.27g, 0.36g and 0.44g were added in the reactors B, C, D and E correspondingly, and reactor A without sucrose addition was used as the control .Results for experiment 1 revealed that reactor A produced largest volume of biogas (1.93L) followed by reactor B with least amount of urea where 1.37L of biogas was generated. Other reactors produced smaller volume of biogas during the study period. For experiment 2 results indicated large volume of biogas (2.72L) was produced in reactor C with 0.27g of sucrose followed by reactor D (2.71L) with 0.36g sucrose. The biogas produced contained 68.9% - 74.6% methane (CH4). This study concluded that addition of nitrogen source does not increase biogas production from Banana winery effluent while addition of carbon source is important as a source of energy for enhancing C: N ratio for process stability and biogas production.Item Anaerobic treatment of tannery wastewater using ASBR for methane recovery and greenhouse gas emission mitigation(Elsevier, 2017-10) Mekonnen, Anduale; Letaa, Seyoum; Njau, KaroliThe objective of this study was to develop and optimize a pilot scale Anaerobic Sequencing Batch Reactor (ASBR) for the treatment tannery wastewater and reduction of greenhouse gas emission. The performance of the pilot scale ASBR was evaluated at the OLRs of 1.03, 1.23, 1.52 and 2.21 kg m−3 d−1 under mesophilic condition (31 °C). The removal efficiencies of COD and methane yield in the pilot scale ASBR were in the range of 69–85% and 0.17 ± 0.2–0.30 ± 0.02m3/kg COD removed, respectively. The optimum COD removal and methane yield were obtained at OLR of 1.03 kg m−3 d−1 (HRT of 4 days) in the stepwise feeding mode. The maximum amount of COD (83.3 ± 3.6%) converted to methane was also obtained in the same loading rate. At this OLR, the volumetric methane production would be 148,190 m3 per year when the digester will be operated at full scale level. The total amount of GHG emission reduction from factory is estimated in the range between 1500 and 3032 tons CO2-eq per year. Generally, the results of this study showed that ASBR is efficient on generating biogas and reducing greenhouse gas emission while treating high strength wastewater such as tannery. Hence, a full scale ASBR should be developed and used to treat the wastewater generated in the tanning industries.Item Analysis of Different Techniques for Improving Performance of Flat Plate Solar Collectors for Fruits Drying(Tanzania Journal of Engineering and Technology (TJET), 2014-06) Bakari, Ramadhani; Minja, Rwaichi; Njau, KaroliFruits drying had become a broader technology in fruits and vegetables value addition. The technology is reported to be a promising way of dying without incurring higher cost but its adaptation has not been feasible in rural areas. Solar dryers have been developed but its poor performance limits its applicability. In this study, several techniques for modifications of traditional solar collector were addressed. It was observed that, varying collector designs in different techniques, a range of collector performances can be employing double duct counter flow, compared to conventional collectors. Likewise performance difference between conventional collectors and studied models were found to be 8%, 7.2%, 6.1% and 5.2% for model parked with charcoal 5 mm wire mesh, 4mm glass thickness and 8 baffles respectively. This study shows that, double duct counter flow system is the best option for improving the performance of the collectors, followed by charcoal and wire mesh. On the hand, using 4 mm glass thickness gave improved performance, however, it is recommended for collector size not exceeding 2 m in length.Item An Analysis of Fuel Properties of Fatty Acid Methyl Ester from Manketti Seeds Oil(Taylor & Francis Online, 2014-11-20) Kivevele, Thomas; Huan, ZhongjieThe fatty acid methyl esters (FAME)produced from vegetable oils, animal fats, or waste oils known as biodiesel has attracted attention as possible replacement of fossil fuels. The fuel properties of biodiesel are similar to that of conventional petro-diesel and it is more environmentally friendly. This study investigated in detail the fuel properties of biodiesel from less common edible oil produced from Manketti seeds (Schinziophyton rautanenii). Manketti Oil Methyl Ester (MOME) was produced by transesterification process using an alcohol in the presence of a catalyst. The fuel related properties of MOME were determined and compared with the global biodiesel standards such as ASTM 6751 and EN 14214. Also, the effects of different antioxidants; 1, 2, 3 tri-hydroxy benzene (Pyrogallol, PY), 3,4,5-tri hydroxy benzoic acid (Propyl Gallate, PG) and 2-tert butyl-4-methoxy phenol (Butylated Hydroxyanisole, BHA) were investigated on oxidation stability, kinematic viscosity and cetane number (CN) of MOME. The results showed that, most of the determined fuel properties fulfilled the minimum requirement of global biodiesel standards. Among antioxidants used in this study, PY and PG were more effective compared to BHA on oxidation stability. Also, addition of antioxidants on MOME showed positive results on CN which was increased and kinematic viscosity was decreased. In summary, biodiesel produced from manketti seeds oil indigenous to Southern Africa can be used as partial substitute of mineral diesel.Item Analysis of land use and land-cover pattern to monitor dynamics of Ngorongoro world heritage site (Tanzania) using hybrid cellular automata-Markov model(Elsevier, 2022) Mwabumba, Mohamed; Yadav, Brijesh; Rwiza, Mwemezi; Larbi, Isaac; Twisa, SekelaAssessment of land-use and land-cover (LULC) change of any region is one of the prominent features used in environmental resource management and its overall sustainable development. This study analyzed the LULC changes of Ngorongoro Conservation Area (NCA) and its surroundings using Remote Sensing and Geographical Information System integrated with Cellular Automata-Markov model. The LULC maps for the years 1995, 2005, and 2016 were classified using unsupervised and supervised classification procedure, and projected for 2025 and 2035 under business-as-usual scenario using the CA–Markov model. The results indicated maximum gains and losses in cultivated land and woodland in the study duration, respectively. The projected LULC for the period 2025 to 2035 showed a reduction in bushland, forest, water, and woodland, but an intensification in cultivated land, grassland, bare land, and the built-up area. The natural forests with high environmental values were found to be continuously declining under the current land management trend, causing the loss in the NCA’s ecological values. For sustainable management, the authorities must reach conciliation between the existing LULC patterns change and ecosystem services monitoring. A rational land use plan must be made to control the increase of cultivated land and built-up area counting a rational land use plan and ecosystem services protection guidelines. Decision makers should involve stakeholder to support improved land use management practices for balanced and sustainable ecosystem services strategies.Item Analysis of Macro- and Microplastics in Riverine, Riverbanks, and Irrigated Farms in Arusha, Tanzania(Springer Nature Switzerland AG., 2021-11-16) Kundu, Mercy; Komakech, Hans; Lugomela, GeorgeMicroplastics and macroplastics have been reported in different urban rivers and agricultural soil across the globe. However, the interlink between them has not been previously assessed. The present study evaluated the relationship between macro- and microplastics in the surface water and sediments in riverine, riverbanks, and soils from irrigated farms in Arusha, Tanzania. Detached pieces from macroplastics and suspected particles of microplastics from the samples were analyzed using the total attenuated reflectance–Fourier transform infrared spectroscopy. Statistical analysis showed that the number of microplastics in the sediments was higher than those in the surface water and that in irrigated farms was of four times higher than those found in riverine. Besides, the numbers of microplastics and macroplastics in the irrigation farms were exponentially related, while the macroplastics from the riverbanks had an inverse relationship with the rivers' profile elevation. Macroplastics of polyethylene type dominated in the riverbanks and irrigated farms with an occurrence frequency of 100%, while polystyrene was abundant in all analyzed microplastics samples. In addition, those irrigation farms adjacent to canals had a significant number of microplastics and macroplastics than the distant farms. This study provides new information for the region and others that divert water from an urban river for irrigation.Item Analysis of spatial and temporal trend of hydro‑climatic parameters in the Kilombero River Catchment, Tanzania(Springer Nature Limited, 2023-05-15) Sigalla, Onesmo; Valimba, Patrick; Selemani, Juma; Kashaigili, Japhet; Tumbo, MadakaInadequate knowledge on actual water availability, have raised social-economic conficts that necessitate proper water management. This requires a better understanding of spatial–temporal trends of hydro-climatic variables as the main contributor to available water for use by sectors of economy. The study has analysed the trend of hydro-climatic variables viz. precipitation, temperature, evapotranspiration and river discharge. One downstream river gauge station was used for discharge data whereas a total of 9 daily observed and 29 grided satellite stations were used for climate data. Climate Hazards Group InfraRed Precipitation was used for precipitation data and Observational Reanalysis Hybrid was used for Temperature data. Mann–Kendall Statistical test, Sen’s slope estimator and ArcMap Inverse Distance Weighted Interpolation functionality were employed for temporal, magnitude and spatial trend analysis respectively. Results confrmed that, spatially, there are three main climatic zones in the study area viz. Udzungwa escarpment, Kilombero valley and Mahenge escarpment. On temporal analysis, with exception of the declining potential evapotranspiration trend, all other variables are on increase. This is with catchment rates of 2.08 mm/year, 0.05 °C/year, 0.02 °C/year, 498.6 m3 /s/year and − 2.27 mm/year for precipitation, Tmax, Tmin, river discharge and PET respectively. Furthermore, rainfalls start late by a month (November) while temperatures picks earlier by September and October for Tmax and Tmin respectively. Water availability matches farming season. However, it is recommended to improve water resources management practices to limit fow impairment as expansions in sectors of economy are expected. Furthermore, landuse change analysis is recommended to ascertain actual trend and hence future water uptake.Item Analysis of spatio-temporal climate variability of a shallow lake catchment in Tanzania(IWA Publishing, 2021) Nyembo, Latifa; Larbi, Isaac; Rwiza, MwemeziThis study analyzed the trends and spatio-temporal variability in rainfall and temperature, and the length of the rainy season (LRS) in the Lake Manyara catchment, Tanzania, covering a period between 1988 and 2018 using stations and satellite climate product. The Mann-Kendall statistical test, Sen's slope estimator, and inverse distance weighting interpolation techniques were used to detect the trends, magnitude of trends and spatial distribution of rainfall and temperature. A modified Stern's method and water balance concept were used for rainfall onset, cessation and LRS analysis, while a standardized precipitation index (SPI) was used to investigate the wetness or dryness of the area. The results showed high variability and decreasing trend (4 mm/y) in annual rainfall, and non-significant increasing trend for minimum and maximum temperature. Rainfall increased from the western to the northern part of the catchment whereas a reversal pattern was noticed for temperature. The SPI shows a signal of normal condition (about 65%) for all stations – with few years showing evidence of wetter and drier conditions. The LRS showed a decreasing trend indicating a potential negative influence on rain-dependent activities. There is a need, therefore, for adaptation measures such as improving water productivity and irrigation at the farm and catchment level.